Phosphorus fractionation in sediments of the Pichavaram mangrove ecosystem,south-eastern coast of India     

Rajesh Kumar Ranjan  AL. Ramanathan  Rita Chauhan  Gurmeet Singh 《Environmental Earth Sciences》2011,62(8):1779-1787

Present study examined phosphorus dynamics through delineation of source as well as availability of phosphorus and its fractionation within the intertidal sediments of Pichavaram mangrove ecosystem. Twelve sediment samples and two cores were collected from the mangrove forest along with estuarine area (Vellar-Coleroon) during January 2005. Sediments were analyzed for total phosphorus and its fractionation using operationally defined chemical sequential extraction scheme (SEDEX). Dissolved phosphorus (in water) and total phosphorus (in sediments) concentrations were high in the Vellar region of Pichavaram mangrove area due to pollution load from nearby villages and agricultural fields. However, the spatial variation in dissolved phosphorus were insignificant (at significance level = 0.05). The results for the phosphorus fractionation (post-tsunami) were compared with earlier studies (pre-tsunami). It was observed that all phosphorus fractions (except adsorbed-phosphorus) showed a highly significant (at significance level = 0.05) increase in concentration after the tsunami event. There was significant decrease in the adsorbed phosphorus concentration as a result of tsunami. The changes were more pronounced for organic phosphorus which increased by almost twofold following the event. These variations were attributed to change in salinity, increase in dissolved oxygen as well as the retreat of tsunami water carrying the waste load. The vertical distribution of phosphorus through core sediments showed that mixing after tsunami had altered the different phosphorus fraction and its availability. Overall, the study indicated that the fluvial weathering along with litter degradation and anthropogenic sources controlled the biogeochemistry of phosphorus in this mangrove ecosystem. Observed changes in the concentrations are a result of altered physico-chemical characteristics caused by tsunami.  相似文献   

Preliminary studies on the characterization of clay minerals in the Sundarban mangrove core sediments,West Bengal,India     

K. Rajkumar  AL. Ramanathan  P. N. Behera  S. Chidambaram 《Arabian Journal of Geosciences》2014,7(2):537-544

Clay mineral found in rivers, estuaries, and marine sedimentary environments is an important group of minerals which is the by-product of chemical weathering. The main constituents of this fine-grained sediment include mudstones, clay stones, and shales. This is probably the first report of a Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) investigation on the clay minerals to characterize them in the Sundarban mangrove core sediments of Moipith Matla and Belamati Island. This study was carried out in the selected stretch for FTIR and SEM analyses. The study reveals the dominant association of kaolinite with subordinate amount of quartz, illite, and chlorite. The abundance of kaolinite, illite, chlorite, and clay with quartz helps in increasing the sediment in the island region. The geochemical and mineralogical evolution of mangrove sediment results in the interaction of biotic and abiotic parameters, whose balance is conditioned by the climate that governs the hydrologic regime, the sedimentation dynamics, and of the organic matter. This study on the characterization of clay provides substantial impact in the water-holding capacity, productivity, and mineralogical and chemical transformation in order to establish much more and intermediate equilibrium between marine influence and continental contribution, as a part of the estuarine environment.  相似文献   

Organic matter characterization in a tropical estuarine-mangrove ecosystem of India: Preliminary assessment by using stable isotopes and lignin phenols   总被引：1，自引：0，他引：1  

M. Bala Krishna Prasad  A.L. Ramanathan 《Estuarine, Coastal and Shelf Science》2009,84(4):617-624

In order to characterize the sources and fate of organic matter (OM) in the Pichavaram estuarine-mangrove ecosystem (east coast of India), stable isotope (δ¹³C and δ¹⁵N) ratios and molecular lignin analyses were conducted in plant litter, benthic algae, sediment, particulate matter and in a variety of benthic invertebrate species. The δ¹³C signature of plant litter ranges from −29.75‰ to −27.64‰ suggesting that mangrove trees follow the C₃ photosynthetic pathway. Sedimentary δ¹³C signature (−28.92‰ to −25.34‰) demonstrates the greater influence of plant litter organic matter on sedimentary organic matter. Suspended particulate organic pool was influenced by terrestrial source and also seems to be influenced by the marine phytoplankton. Enriched signature of δ¹⁵N in surface sediments (4.66–8.01‰; avg. 6.69‰) suggesting the influence of anthropogenic nitrogen from agricultural fields and human settlements. Spatial chemical variability in availability of nitrogen and plant associated microbial interactions demonstrate variability in δ¹⁵N signature in mangrove plant litter. Two (lower and higher) trophic levels of invertebrates were identified with and observed >4‰ gradient in δ¹³C signal between these two trophic groups. The observed δ¹³C values suggest that the lower level invertebrates feed on phytoplankton and higher level organisms have a mixed source of diet, phytoplankton, sediment and particulate organic matter. Lignin phenol analyses explain that the benthic surface layer was almost free of lignin. The ratio between syringyl phenols to vanillyl phenols (S/V) is 1.14–1.32 (avg. 1.23) and cinnamyl phenols to vanillyl phenols (C/V) is 0.17–0.31 (avg. 0.24), demonstrate non-woody angiosperm tissues was the major sources of lignin to this ecosystem, while aldehyde to acid ratios (Ad/Al) describe diagenetic nature of sediment and is moderately to less degraded. A two-end-member mixing model indicate that the terrigenous OM was dominant in the estuarine zones, while in the mangrove zone terrigenous supply accounts for 60% and marine input accounts for 40%.  相似文献   

Characterization of clay minerals in the Sundarban mangroves river sediments by SEM/EDS     

K. Rajkumar  A. L. Ramanathan  P. N. Behera 《Journal of the Geological Society of India》2012,80(3):429-434

Clay minerals, byproducts of chemical weathering, are important group of minerals found in rivers, estuaries, and marine sedimentary environments, which include mudstones, clay stones, and shales. In the present study, FTIR and SEM investigation on the clay minerals in Sundarban mangrove core sediments collected from Moipith Matla and Belamati Island are carried out. The study indicated the dominant association of kaolinite with subordinate amount of quartz, illite and chlorite. The abundance of kaolinite, illite chlorite and clay with quartz helps in increasing sediment in the islands region. The geochemical and mineralogical evolution of mangrove sediments are results of the interaction of biotic and abiotic parameters, whose balance is conditioned by the climate that governs the hydrologic regime, the sedimentation dynamics and the organic matter. This study on the charaterstation of clay provides us with substantial impact in the water holding capacity, productivity and mineralogical and chemical transformation in order to establish much more and intermediate equilibrium between marine influence and continental contribution, as part of the estuarine environment, than to the tropical climate conditions.  相似文献   

Qualitative and quantitative assessment of TanDEM-X DEM over western Himalayan glaciated terrain     

Pratima Pandey  Surendar Manickam  Avik Bhattacharya  AL. Ramanathan  Gulab Singh  G. Venkataraman 《国际地球制图》2017,32(4):442-454

Glaciers have a high impact in the socio-economic sectors including water supply, energy production, flood and avalanches. A high precision digital elevation model (DEM) is required to monitor glaciers and to study various glacier processes. The present study deals with the qualitative and quantitative evaluation of the DEM generated from the bistatic TanDEM-X data by comparing it with GPS, Ice, Cloud, and land Elevation Satellite (ICESat) data and standard global DEMs such as Shuttle Radar Topography Mission (SRTM) and Advanced Space-borne Thermal Emission and Reflection Radiometer Global DEM (ASTER GDEM). The study area consists of highly undulating glaciated terrain in western Himalaya, India. The results reveal that TanDEM-X is slightly better than SRTM both qualitatively and quantitatively, whereas ASTER GDEM showing maximum discrepancy among the three DEMs. The Root Mean Square Error (RMSE) of the TanDEM-X DEM with respect to GPS is 3.5 m at lower relief and 11.9 m at glaciated terrain, against 6.7 and 12.5 m for SRTM and 9.3 and 19.8 m for ASTER GDEM, respectively, for the same sites. On an average, for the whole study area, the RMSE of TanDEM-X is 7.9 m, SRTM is 9.3 m and ASTER GDM is 14.2 m. The RMSE of TanDEM-X, SRTM and ASTER GDEM with respect to ICESat are 16.3, 19.9 and 101.1 m, respectively. It is evident from the analysis that though SRTM is closer to TanDEM-X in terms of accuracy in the mountainous terrain, however, TanDEM-X will be more useful for studying glacier dynamics and topography.  相似文献   

Ageostrophic instabilities in a two fluid system with rotation     

N. Ramanathan  D. B. Rao 《Journal of Earth System Science》1984,93(4):387-397

The stability of synoptic scale waves formed on a frontal surface is studied including nongeostrophic effects with the basic flow subjected to both vertical and horizontal shear. Spectral method is used to obtain the desired solutions. The stability characteristics of the developed unstable modes are presented as a function of shears of the basic flow. With the inclusion of barotropic shear the spectrum of instabilities increase. The lower speeded member of the mixed mode (gravitational-rotational) pair is influenced by the barotropic shear in the basic current and it appears at lower vertical shears. The structure of the height perturbations are utilized to distinguish the various unstable modes developed in the system together with their stability characteristics. This investigation has shown that the ageostrophic effects can be a significant factor in the development of synoptic scale waves on a frontal surface.  相似文献   

Geochemistry of the Cauvery Estuary,East Coast of India     

A. L. Ramanathan  P. Vaithiyanathan  V. Subramanian  B. K. Das 《Estuaries and Coasts》1993,16(3):459-474

Major ion chemistry of water and elemental geochemistry of suspended and surficial sediments collected from the Cauvery Estuary were studied to understand the geochemical processes in this tropical estuarine system. Specific conductance (EC), total dissolved solids (TDS), and total suspended matter (TSM) increased conservatively with increasing chlorinity. In general, SO₄ ^2?, Na, K, Ca, and Mg showed an increasing trend while H₄SiO₄ and PO₄ ^3? showed a decreasing trend toward the sea. Additional removal mechanisms operating for these ions in the Cauvery Estuary have been identified based on observed concentrations. Factor analysis pointed out the sources contributing to the observed trends in estuarine water chemistry. POC and PON decreased toward the high chlorinity zone. TSM in the Cauvery Estuary were mostly of inorganic nature. Stable carbon isotope values showed that the carbon was equally of marine and terrestrial origin and helped to delineate the contribution of river water and seawater. The ? mean size (a logarithmic grain size scale commonly used by sedimentologists) indicated that the surficial sediments were primarily comprised of coarse and silt, whereas suspended sediments were principally silt and clay. Suspended sediments were enriched in clays compared to surficial sediments. Quartz and feldspar were abundant among detritals while chlorite, kaolinite, and montmorillonite were dominant among clays. Silicon was the most abundant element in the sediments followed by Al, Ca, Na, K, Fe, Mn, and P. Heavy metals were enriched in the suspended sediments compared to the surficial bottom sediments as follows: Fe = 3.5, Mn = 7.4, Pb = 1.1, Zn = 15.2, Cu = 7.4, and Cr = 4.0. The levels of Cd, Cr, Zn, and Fe increased up the middle reaches and then decreased toward the sea due to urban effluent and fertilizer input. Size fractionation studies indicated that the metal concentration in the finer fraction was 50% higher by mass than the coarse silt and fine silt fractions. Chemical fractionation studies showed that the abundance of metals were in the order of residual > organic/sulfide > carbonate > Fe/Mn oxide > exchangeable fractions.  相似文献   

Heavy metal distribution in the Godavari River basin     

G. Biksham  V. Subramanian  A. L. Ramanathan  R. Van Grieken 《Environmental Geology》1991,17(2):117-126

Suspended and bed sediments collected from the entire region of the Godavari River basin were analyzed for Fe, Mn, Cr, Cu, Ni, and Zn. There are pronounced temporal and spatial variations in the heavy metal distributions. The concentrations of heavy metals in the suspended sediments are significantly higher than the bed sediments.Throughout the basin heavy metals are enriched in the finer fractions (<2 µm) of the bed sediments. The average heavymetal composition of the sediments is higher when compared to the average Indian river sediments. Heavy-metal concentration in the two shallow cores collected shows, to some extent, the influence of urbanization. When compared to the other tropical Indian rivers such as the Krishna, the Godavari appears to be a significant contributor of heavy metals to the Bay of Bengal. Considering the enormous sediment load of the Godavari River—170 million tons/yr, the heavy metal fluxes to the Bay of Bengal is very significant. Except for the Pranhita, other tributaries of the Godavari do not contribute significant loads of heavy metals. All the metals show high correlation among themselves and the correlation is more pronounced in suspended sediments than in the bed sediments. The heavy-metal distribution, fractionation, and its relationship with total suspended sediments and depth in various parts of the basin are discussed in detail.  相似文献   

Unsteady state of glaciers (Chhota Shigri and Hamtah) and climate in Lahaul and Spiti region,western Himalayas: a review of recent mass loss     

Arindan Mandal  AL. Ramanathan  Thupstan Angchuk  Mohd Soheb  Virendra Bahadur Singh 《Environmental Earth Sciences》2016,75(17):1233

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Assessment of groundwater quality of Lakshimpur district of Bangladesh using water quality indices,geostatistical methods,and multivariate analysis     

Mohammad Amir Hossain Bhuiyan  Md. Bodrud-Doza  A. R. M. Towfiqul Islam  M. A. Rakib  M. Safiur Rahman  A. L. Ramanathan 《Environmental Earth Sciences》2016,75(12):1020

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